She was accompanied by her partner Brad Pitt.
She accessorized with matching Salvatore Ferragamo pumps and spectacular rectangle earrings by her personal jewelry designer Robert Procop.
Speaking to the media at the premiere about her makeover in the film, Jolie said, "I had never played a lady... really... before... I had played a version of a kind of a girl... something really tough, or something cool."
"I found it a big challenge to play someone extremely European, elegant, little bows and little pink. It was all very foreign to me," she added.
Speaking about working with co-star Johnny Depp - who looked dapper at the event in a 3 piece pin stripe Polo Ralph Lauren suit - Jolie said they both had seen and liked each other's films but had never met before.
"And we met and we talked about kids for the first hour and France for the second and had a good laugh. We really enjoyed working with each other in the film and I hope that comes across," she added.
The film is due in theaters on December 10.
